Interface control and mechanical properties of Al2O3-Ni laminated composites that were prepared through gel casting and hot pressing

摘要

The use of ceramic-metal laminated composites is an efficient way to improve the toughness of brittle ceramics. Uniform multilayered Al2O3-Ni laminated composites were prepared through a combined method of gel casting and hot pressing, which is less cumbersome than the traditional sequential lamination method. The wettability, diffusion and chemical reaction between Al2O3 and Ni were controlled through surface oxidation treatment of the Ni sheets. The results show that when the surface-oxidized Ni sheets were used, the microstructure of the Al2O3-Ni interface changed with the hot-pressing temperature. As the hot-pressing temperature was increased from 1150 to 1300 degrees C, a straight and clean interface formed, the interface became interlocked and, finally, a stable layer of NiAl2O4 formed at the interface. The interlocked microstructure was especially beneficial for interfacial bonding, and the plastic deformation of the Ni layers was restrained, thereby leading to slip steps rather than dimple formation on the fracture surfaces of the Ni layers. In addition, the toughening effects of plastic deformation and crack deflection in the Al2O3-Ni laminated composites were significant, which resulted in ductile fracture rather than brittle fracture. As a result, the Al2O3-Ni laminated composite that was prepared using the oxidized Ni sheets and the combined method of gel casting and hot pressing achieved a higher work of fracture than laminated composites that were prepared via other methods.