Abstract AA6101 Al alloy is widely used as a high-strength conductive aluminum alloy, and the contents and existence of Mg and Si can influence its electrical conductivity and mechanical properties obviously. In this paper, experiments were conducted to find the optimal Mg, Si additions and Mg/Si ratio and then combined with heat treatment to improve the EC and mechanical properties at the same time. Firstly, considering the proper Mg/Si ratio, two optimal Mg and Si additions were determined: Al–0.7Mg–0.5Si and Al–0.4Mg–0.7Si with EC of 51.5%IACS and 51.4%IACS, and through homogenization treatment, their EC improved to 57.0%IACS and 55.7%IACS, respectively. Then, appropriate Fe was added to further control Si to achieve the balance of EC and mechanical properties. Results showed that for AA6101 Al alloy the ideal Mg/Si mass ratio was 1.4 and high Mg and low Si can obtain good EC and mechanical properties. Besides, it can be found that at low Mg/Si ratio, the alloy conductivity takes longer to reach its peak hardness. So the best performance Al–0.7Mg–0.5Si–0.2Fe alloy was obtained within the range of AA6101 national standard. The EC of Al–0.7Mg–0.5Si–0.2Fe can reach 56.3%IACS, and hardness is 91.3 Hv. Based on the study, a schematic diagram was drawn to analyze the influence mechanisms of Mg, Si and Fe on EC and hardness of AA6101 Al alloy.
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