Dynamically vulcanized polylactic acid/natural rubber/waste rubber blends: Effect of the crosslinking agent on the morphology and tensile properties

摘要

PLA/natural rubber (NR)/wastes tire rubber (GTR) were dynamically vulcanizing using dicumyl peroxide (DCP). Swelling, dissolution, and electron microscopy revealed that the unvulcanized and weekly vulcanized blends (DCP 3 wt%) show co-continuous rubber/PLA phase. In the latter blends, the tensile toughness (1.3 MJ m(-3)) and the tensile-impact strength of the neat PLA (58 kJ m(-2)) were increased of a factor 12.5 and 8.3 respectively. Moreover, the appropriate crosslinking agent content (3-3.75 wt%) in the ternary blends allowed to reach same tensile toughness, impact strength, shape recovery and shape fixity as compared to their equivalent binary PLA/NR blends.