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Synthesis of silver nanoparticles by atmospheric pressure plasma jet

机译:常压等离子体射流合成银纳米粒子

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摘要

Silver nanoparticles are one of the most extensively used metallic nanomaterials due to their unusual physical and chemical properties as well as their promising applications in a wide range of different fields. In this study, a non-thermal atmospheric pressure helium plasma jet was used to successfully synthesize silver nanoparticles with silver nitrate as a precursor and trisodium citrate as a capping agent. The browning of the solution after only 5 min of plasma irradiation is a result of the surface plasmon resonance (SPR) from the obtained silver nanoparticles. The SPR was confirmed by the presence of an absorption band in the visible range between 400 and 450 nm demonstrated in the UV-vis spectra. The effect of different chemical parameters such as the concentration of silver nitrate and the concentration of citrate on the silver nanoparticles have been studied. These nanoparticles were further characterized using transmission electron microscopy and dynamic light scattering. Therefore, the plasma jet was advantageous to fast produce silver nanoparticles in friendly conditions. In addition, the used experimental setup allows further studies in different solvents conditions and with different capping agents. So, this methodology could be useful for the preparation of silver nanoparticles required for numerous applications such as bioactivity, catalysis, surface enhanced Raman scattering, and photonic.
机译:银纳米颗粒是应用最广泛的金属纳米材料之一,因为它具有不寻常的物理和化学性质,并且在广泛的不同领域都有广阔的应用前景。本研究采用非热常压氦等离子体射流成功合成了以硝酸银为前驱体、柠檬酸三钠为封端剂的纳米银颗粒。等离子体照射仅5分钟后溶液的褐变是所获得的银纳米颗粒表面等离子体共振(SPR)的结果。在紫外-可见光谱中,可见光范围内存在400至450 nm之间的吸收带,证实了SPR。研究了硝酸银浓度和柠檬酸银浓度等不同化学参数对纳米银颗粒的影响。利用透射电子显微镜和动态光散射进一步表征了这些纳米颗粒。因此,等离子体射流有利于在友好的条件下快速产生银纳米颗粒。此外,所使用的实验装置允许在不同的溶剂条件和不同的封端剂下进行进一步研究。因此,这种方法可用于制备生物活性、催化、表面增强拉曼散射和光子学等众多应用所需的银纳米颗粒。

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