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Sustainable synthesis of silver decorated graphene nanocomposite with potential antioxidant and antibacterial properties

机译:可持续合成具有潜在抗氧化和抗菌特性的银装饰石墨烯纳米复合材料

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摘要

In the pursuit of graphene-silver nanocomposites, Kigelia Africana stem extract was utilized for the sustainable synthesis of reduced graphene oxide-silver (KARG-Ag) nanocomposite. The UV-Visible spectra exhibited both graphene and Ag peaks at lambda(max) of 268 and 406 nm respectively, Raman spectra exhibited both D and G bands with an I-D/I-G ratio of 1.21. The XRD spectra showed the graphene peak at 2 theta = 26 degrees along with Ag peaks with an average particle size of 21.3 nm. Well stabilized Ag nanoparticles deposited on the transparent KARG sheets were further identified by TEM analysis. Thus, all the spectroscopic techniques proved the synthesis of said nanocomposite. The KARG-Ag nanocomposite (500 mu g/mL) showed superior total antioxidant activity (TAA-136) than the standard ascorbic acid (100) or KARG (82) and potential antibacterial activity against four different strains. Hence, the present green method and the potential applications of KARG-Ag nanocomposite may find environmental and clinical applications.
机译:在追求石墨烯-银纳米复合材料的过程中,非洲桔梗提取物被用于还原氧化石墨烯-银(KARG-Ag)纳米复合材料的可持续合成。紫外-可见光谱分别在λ(max)和406 nm处表现出石墨烯峰和Ag峰,拉曼光谱在D波段和G波段均表现出I-D/I-G比值为1.21。XRD谱图显示石墨烯峰在2 θ = 26度处,银峰的平均粒径为21.3 nm。通过透射电镜分析进一步鉴定了沉积在透明KARG片上的稳定良好的Ag纳米颗粒。因此,所有的光谱技术都证明了所述纳米复合材料的合成。KARG-Ag纳米复合材料(500 μ g/mL)的总抗氧化活性(TAA-136)优于标准抗坏血酸(100)或KARG(82),对4种不同菌株具有潜在的抑菌活性。因此,目前的绿色方法和KARG-Ag纳米复合材料的潜在应用可能在环境和临床上得到应用。

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