首页> 外文期刊>Australian Journal of Chemistry: A Journal for the Publication of Original Research in All Branches of Chemistry >CP-225,917 and CP-263,114 Synthesis Support Studies:Testing a Radical Cyclization Strategy for Installation of the Side-Chains
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CP-225,917 and CP-263,114 Synthesis Support Studies:Testing a Radical Cyclization Strategy for Installation of the Side-Chains

机译:CP-225,917和CP-263,114综合支持研究:测试侧链安装的自由基环化策略

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摘要

The selenocarbonate (18) has been prepared and shown to react with hexabutyldistannane hydride/allyltributylstannane to give,via a radical cyclization/allylation sequence,the lactone (21) embodying vicinal and trans-related functionality likely to be appropriate for elaboration to the side-chains associated with the title compounds (1) and (2) (phomoidrides A and B).
机译:制备了硒代碳酸酯(18),并显示出与六丁基二氢化锡氢化物/烯丙基三丁基锡烷反应,通过自由基环化/烯丙基化顺序生成内酯(21),该内酯具有邻位和反式相关的功能,可能适合于侧-与标题化合物(1)和(2)相关的链(拟膦酸酯A和B)。

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