Synthesis and Characterization of Tetrakis(allyloxy) Substituted Zn(II), Pt(II) and Pd(II) Phthalocyaninates

摘要

abstract_textp2(3)-Tetrakis(allyloxy) substituted phthalocyanine complexes of Zn(II), Pt(II) and Pd(II) have been obtained from a phthalocyanine ligand in high yields (up to 90 %). Both thermal and microwave irradiation techniques were successfully applied for complexes of Pd(II). Platinum and palladium complexes were synthesized for the first time and the new method for the synthesis of zinc complex was proposed. The obtained compounds were characterized by a combination of MALDI/TOF mass spectrometry, UV-Vis, and Pt-195 NMR spectroscopies. Photochemical properties of platinum(II) phthalocyanine were investigated. It was shown that this complex maintained high production of singlet oxygen and potentially can be used in photodynamic therapy./p/abstract_text