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The impact of sulphonation and hot-pressing on low-energy high-temperature chemi-thermomechanical pulp

机译:磺化和热压对低能高温化学热机械浆的影响

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Abstract Hot-pressing high-yield pulp-based paper, at a temperature well above the softening temperature of lignin, increases paper density and strength. Here, it is investigated whether improved paper strength can be achieved and whether lower pressing temperatures can be?used in combination with the increased sulphonation of?high-temperature chemi-thermomechanical pulp (HTCTMP). Moist paper sheets from low-energy Norway spruce HTCTMP were hot pressed at temperatures up to 270?°C. Sulphite charges of 25–120?kg/bdt were used during impregnation, preheating, and refining at 180?°C with an electric energy demand of 370–500?kW?h/bdt to a shive content of 1. The pulps were mixed with 20 bleached unrefined kraft pulp to ensure that the sheet formation would not be hampered by the pulp coarseness. A tensile index of 70 kN?m/kg was reached with the highest sulphite dosage at a pressing temperature of only 150?°C, versus 60 kN?m/kg for the corresponding market CTMP. To obtain high wet strength, the highest temperature was required, while the sulphite charge was found to be of minor importance. This study has shown that it is possible to obtain strong and wet-stable paper products from HTCTMP, with a yield of 94–96 and a low energy demand at reduced pressing temperature.
机译:摘要 热压高产量纸浆基纸在远高于木质素软化温度的温度下,可提高纸张的密度和强度。本文研究了是否可以提高纸张强度,以及是否可以将较低的压制温度与高温化学热机械浆(HTCTMP)的磺化增加结合使用。低能耗挪威云杉HTCTMP的湿纸在高达270°C的温度下进行热压。 在180°C的浸渍、预热和精炼过程中,使用25-120?kg/bdt的亚硫酸盐电荷,电能需求为370-500?kWh/bdt,含量为1%。将纸浆与20%漂白的未精制牛皮纸浆混合,以确保纸浆的形成不会因纸浆粗糙而受阻。在仅150°C的压制温度下,亚硫酸盐用量最高,拉伸指数达到70 kN?m/kg,而相应的市场CTMP为60 kN?m/kg。为了获得高湿强度,需要最高温度,而亚硫酸盐电荷则不重要。这项研究表明,从HTCTMP中获得坚固且耐湿的纸制品是可能的,收率为94-96%,在降低压制温度时能耗低。

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