Influence of noble metals on thermoacoustic oscillations and boundaries of the region of negative temperature coefficient during combustion of n-pentane-air mixtures

摘要

Using the combustion of n-pentane - air mixtures as an example, it was shown that thermoacoustic regimes of ignition disappear in the presence of a platinum surface, which generates catalytic centers propagating into the volume. Thus, the platinum catalyst eliminates a certain stage of kinetic mechanism, and the negative temperature coefficient phenomenon vanishes. In the presence of a palladium catalytic surface that does not generate catalytic centers propagating into the volume, the phenomenon of a negative temperature coefficient occurs.