AbstractThe effect of substituting Si for B on the electrochemical behaviour of the glassy alloy families Fe‐B and Fe‐Ni‐B has been investigated in solutions with pH ranging from 4 up to 8.4. The influence of the aggressive ions (Cl−and SOu 42−) has also been studied. AES and XPS have been used to further characterize the alloys in order to interpret their behaviour in the variou
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