Synthesis and Characterization of Divalent Organolanthanide-Fullerene Adducts Cp2LnC60(Ln=Yb, Sm): First Example of Insertion Reaction Involving Cyclopentadienyl and Fullerene

摘要

Reaction of equimolar amount of Cp2Ln (Ln˭Yb, Sm) with fullerene C60affords Cp2LnC60(Ln˭Yb, Sm), and insertion reaction involving cyclopentadienyl and fullerene was reported first time.