Oxzirconium(IV) Complexes with Schiff Base of 2-Aminopyridine

摘要

Aseries of new oxozirconium (IV) complexes with a Schiff base derived from 2-aminopyridine,i,e., 2-N-[benzalidene] aminopyridine (BAPy) has been synthesized.Analytical,spectral and conductance studies revealed that complexes have the general composition Zr(OH)_2X_2centre dotnL (X=Br~-,1~-,or NCS~-,n=4;X=NO~-_3,n=L;L=BAPy) after trapping one water molecule.Zr-atom is 8-coordinated in these complexes.Antifugal studies on the reprsentative have been done sucdcessfully.