Four Novel Screw-like Tris(1,10-phenanthroline) Ruthenium(II) Bishexafluorophosphate Derivatives

摘要

Four novel scrow-like Ru(II) complexes,tris(5-lauramide-1,10-phenanthroline)Ru(II) bishexaluorophosphate,tris(5-myristamide-1,10-phenanthroline)Ru(II) bishexafluorophosphate,tris(5-palmi tamide-1,10-phenanthroline)Ru(II)bishexafluorophosphate and tris (5-stearamide-1,10-phenanthroline)Ru(II) bishexafluorophosphate have been efficiently synthesized. They are confirmed by the techniques of IR, ~1H NMR, ~1H-~1H COSY and ES-MS. Also, their electrochemistry,fluorescence and electrochemiluminescence are reported.