Fluoroxysulphate: A Powerful New Oxidant,Kinetic Aspects

摘要

Oxidations are of immeense interest to a wide of synthetic organic chemists.They play a vital role in the various oxidative transformations to specific transformation of different organic substrates and mechanistic studies are clearly a means of developing better synthetic methods. It is only in recent times that aufficient attention is being paid to the mechanistic aspects of oxidationin organic chemistry. Stoichiometric oxidations with metal oxidats such as permanga nate~1 and chromic acid have been widely explored. Many liquid phase oxidants have been studied extensively employing relatively inexpensive sodium hypochlorite~2 and potassium peroxydisulphate oxidants in aqueous media. The synthesis of the fluoroxysulphateion , SO_4F, adds to a rather select list of aqueous oxidants. This review highlights ithe recent work on the reaction chemistry of aqueous fluoroxysulphate.