Synthesis and Crystal Structure of MnL3·(ClO4)2 (L = Diacetyl dihydrazone)

Jian-Hong Bi; Zi-Xian Huang; Meng Li

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Synthesis and Crystal Structure of MnL3·(ClO4)2 (L = Diacetyl dihydrazone)

机译：MnL3·（ClO4）2（L =二乙酰基二hydr）的合成及晶体结构

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A new complex MnL3·(ClO4)2 (L = diacetyl dihydrazone) has been synthesized and characterized by IR spectra,elemental analysis and single-crystal X-ray. The crystal is trigonal,space P-3cl with unit cell parameters: a = 9.6546(4)A,b = 9.6546(4)A,c = 15.3525 (11)A,α = 90°,β = 90°,γ = 120°,V = 1239.30(11)A~3,Z = 2,Mr = 596.32,Dc = 1.598 Mg/cm~3,n = 0.811 mm~(-1),F(000) = 618,T = 293(2) K,R = 0.0481,wR = 0.1627 for 3899 reflections with I > 2σ(I).

机译：合成了一种新型的配合物MnL3·（ClO4）2（L =二乙酰基二hydr），并通过红外光谱，元素分析和单晶X射线表征。晶体为三角形，空间为P-3cl，晶胞参数为：a = 9.6546（4）A，b = 9.6546（4）A，c = 15.3525（11）A，α= 90°，β= 90°，γ= 120°，V = 1239.30（11）A〜3，Z = 2，Mr = 596.32，Dc = 1.598 Mg / cm〜3，n = 0.811 mm〜（-1），F（000）= 618，T = 293 （2）对于I>2σ（I）的3899次反射，K，R = 0.0481，wR = 0.1627。

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《Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry》 |2009年第8期|共3页
作者
Jian-Hong Bi; Zi-Xian Huang; Meng Li;
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正文语种 eng
中图分类化学;
关键词
Manganese(H) complex; Diacetyl dihydrazone; Crystal sructure.;

机译：锰（H）配合物;二乙酰肼;晶体结构。;

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Synthesis and Crystal Structure of MnL3·(ClO4)2 (L = Diacetyl dihydrazone)

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