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A Polymeric Dye of Aqueous Disperse Violet 17-Based Polyurethane Dispersion

机译:水性分散紫17基聚氨酯分散体的聚合物染料

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摘要

A polymeric dye, aqueous disperse violet 17-based polyurethane dispersion (PU-DV17), was synthesized depending on a modified acetone process. The structure of PU-DV17 was confirmed by FT-IR and UV-visible analysis. Due to presence of well-known anthraquinone in PU-DV17, this polymeric dye exhibited intriguing optical behaviour in aqueous solution. The fluorescence intensity of PU-DV17 emulsion was enhanced greatly with contrast to that of DV17. It was found that the fluorescence intensity of PU-DV17 emulsion would decline along with increasing temperature between 20 °C and 40 °C and enhance along with increasing temperature between 40 °C and 90 °C. The fluorescence of PU-DV17 emulsion was very stable and was not sensitive to hydroquinone quencher.
机译:取决于改进的丙酮方法,合成了聚合染料,水性分散紫17基聚氨酯分散液(PU-DV17)。通过FT-IR和UV-可见分析确认PU-DV17的结构。由于在PU-DV17中存在众所周知的蒽醌,因此该聚合物染料在水溶液中表现出令人感兴趣的光学性能。与DV17相比,PU-DV17乳液的荧光强度大大提高。发现PU-DV17乳液的荧光强度将随着温度在20℃至40℃之间的升高而下降,并且随着温度在40℃至90℃之间的升高而增强。 PU-DV17乳液的荧光非常稳定,对氢醌猝灭剂不敏感。

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