Synthesis of a Bridged Tetraaza Macrocycle Cu(II) Complex and Its Molecular Magnetic Properties

Jian-Hong Bi; Wen-Tao Bi; Nai-Liang Hu

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Synthesis of a Bridged Tetraaza Macrocycle Cu(II) Complex and Its Molecular Magnetic Properties

机译：桥联四氮杂大环铜（II）配合物的合成及其分子磁性

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A novel self-assembled tetraaza macrocycle Cu(II) complex: [(CuL)2Fe(SCN)4](ClO4)2 (L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) has been synthesized and characterized by IR spectra and elemental analysis. Its molecular magnetic properties investigation shows that weak antiferromagnetic interactions are mediated between the tetraaza macrocycle Cu(II) ions through the [Fe(SCN)4]~(2-) bridged in the complex.

机译：一种新型的自组装四氮杂大环铜（II）配合物：[[（CuL）2Fe（SCN）4]（ClO4）2（L = 5,5,7,12,12,14-六甲基-1,4,8，已合成11-四氮杂环十四碳四（11-二烯）并通过红外光谱和元素分析对其进行了表征。它的分子磁性研究表明，四氮杂大环铜离子之间的弱反铁磁相互作用是通过复合物中桥接的[Fe（SCN）4]〜（2-）介导的。

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《Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry》 |2012年第2期|共2页
作者
Jian-Hong Bi; Wen-Tao Bi; Nai-Liang Hu;
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正文语种 eng
中图分类化学;
关键词
Copper(II) complex; Tetraza macrocycle; Self-assemble; Magnetic property.;

机译：铜（II）配合物;Tetraza大环;自组装;磁性。;
入库时间 2022-08-18 10:17:44

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1. Synthesis of a Bridged Tetraaza Macrocycle Cu(II) Complex and Its Molecular Magnetic Properties [J] . Jian-Hong Bi, Wen-Tao Bi, Nai-Liang Hu Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry . 2012,第2期

机译：桥联四氮杂大环铜（II）配合物的合成及其分子磁性
2. A new class of macrocycle capable of binding exogenous metals: synthesis, structure, magnetic and electrochemical properties of a Cu(II) trinuclear complex based upon 1, 4, 8, 11-tetraaza-cyclotetradecane-2, 3-dione (exoO_2) cyclam [J] . Leroy Cronin, Andrew R. Mount, Simon Parsons, Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1999,第12期

机译：能够结合外源金属的新型大环化合物：基于1，4，8，11-四氮杂-环十四烷-2，3-二酮（exoO_2）环烷的Cu（II）三核配合物的合成，结构，磁性和电化学性质
3. 1,1-Cyclohexanediacetate as New Bridging Ligand for Assembling of Homo- and Heterometallic Molecular Complexes with Cu (3) (II) , Cu (2) (II) Ln (2) (III) (Ln = Sm or Gd) and Ni (2) (II) Gd (2) (III) Cores: Synthesis, Structure and Magnetic Properties [J] . Gogoleva Natalya, Zorina-Tikhonova Ekaterina, Aleksandrov Grigory, Journal of cluster science . 2015,第1期

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4. Magnetic properties of lanthanoid(III) phthalocyaninato triple-decker complexes in an external magnetic field and electronic transport properties for molecular spintronics [C] . K Katoh, K Yamamoto, T Kajiwara Joint European Magnetic Symposia . 2010

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5. I. THE SYNTHESES, SOLUTION BEHAVIOR, CRYSTAL STRUCTURES AND MAGNETIC PROPERTIES OF SOME IMIDAZOLATE BRIDGED COPPER(II) COMPLEXES. II. THE CRYSTAL STRUCTURE AND MAGNETIC PROPERTIES OF A TRICOPPER(II) CLUSTER CONTAINING A TRIPLY BRIDGING CARBONATE GROUP. [D] . KOLKS, GARY ARNOLD. 1980

机译：I.某些咪唑基桥接铜（II）配合物的合成，溶液行为，晶体结构和磁性。二。含碳桥基的三铜（II）簇的晶体结构和磁性。
6. Ground State Electronic and Magnetic Properties of a μ3-Oxo Bridged Trinuclear Cu(II) Complex: Correlation to the Native Intermediate of the Multicopper Oxidases [O] . Jungjoo Yoon, Edward I. Solomon -1

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7. Synthesis of a Di-N-cyanoethylated Tetraaza Macrocycle Containing Eight C-Methyl Groups and Its Nickel(II) Complex: Effects of the Methyl Groups on Their Properties [O] . 2002

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8. Synthesis, Structure, and Magnetic and Moessbauer Properties of Mononuclear and Asymmetric, Oxo-Bridged Trinuclear Iron(III) Complexes of a New Polyimidazole Ligand [R] . Gorun, S. M., Papaefthymiou, G. C., Frankel, R. B., 1987

机译：新型聚咪唑配体的单核和不对称，桥联三核铁（III）配合物的合成，结构，磁性和穆斯堡尔性质

Synthesis of a Bridged Tetraaza Macrocycle Cu(II) Complex and Its Molecular Magnetic Properties

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