Synthesis and Structural Characterization of a Novel Carboxy-Functionalized Diiron Dithiolate Complex

Pei-Hua Zhao; Ya-Qing Liu; Xin-ang Li

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Synthesis and Structural Characterization of a Novel Carboxy-Functionalized Diiron Dithiolate Complex

机译：新型具有羧基功能的二硫代二铁二铁盐配合物的合成与结构表征

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A novel carboxy-functionalized diiron dithiolate complex, [(μ-SCH2)2NCH2CH2CO2CH2CH2Cl][Fe2(CO)6] (I) as active site model of [FeFej-hydrogenase, has been successfully synthesized by condensation reaction of [(μ-SCH2)2NCH2CH2CO2H][Fe2(CO)6] (A) with H0CH2CH2C1 in the presence of 4-dimethylaminopyridine and dicyclohexylcarbodiimide. Its structure was characterized by combustion analysis, ESI-MS, IR and ~1H (~(13)C) NMR spectroscopic techniques.

机译：[[μ-SCH2）2NCH2CH2CO2CH2CH2Cl] [Fe2（CO）6]（I）作为[FeFej-加氢酶的活性位点]的新型羧基官能化二硫代二铁盐配合物已通过[[μ-SCH2 ）2NCH2CH2CO2H] [Fe2（CO）6]（A）在4-二甲基氨基吡啶和二环己基碳二亚胺存在下与HCH2CH2C1结合使用。通过燃烧分析，ESI-MS，IR和〜1H（〜（13）C）NMR光谱技术表征了其结构。

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《Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry》 |2013年第10期|共3页
作者
Pei-Hua Zhao; Ya-Qing Liu; Xin-ang Li;
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正文语种 eng
中图分类化学;
关键词
Carboxy-functionalized; Diiron dithiolate; Synthesis; Structural characterization.;

机译：羧基官能化;二硫代二硫酸铁;合成;结构表征。;

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1. Synthesis and Structural Characterization of a Novel Carboxy-Functionalized Diiron Dithiolate Complex [J] . Pei-Hua Zhao, Ya-Qing Liu, Xin-ang Li Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry . 2013,第10期

机译：新型具有羧基功能的二硫代二铁二铁盐配合物的合成与结构表征
2. Synthesis and structural characterization of a diiron propane-dithiolate complex [(μ-PDT)Fe_2(CO)_5]_2[(η~5-Ph_2PC_5H_4)_2Fe] containing a bidentate phosphine ligand 1,1'-bis(diphenylphosphino)ferrocene [J] . XU-FENG LIU, BANG-SHAO YIN Journal of Coordination Chemistry . 2010,第23期

机译：含二齿膦配体1,1'-双（二苯基膦基）二茂铁的二铁丙烷-二硫代二铁络合物[（μ-PDT）Fe_2（CO）_5] _2 [（η〜5-Ph_2PC_5H_4）_2Fe]的合成与结构表征
3. Synthesis, characterization and crystal structures of carboxy-functionalized diiron propanedithiolate complexes [J] . Pei-Hua Zhao, Ya-Qing Liu, Gui-Zhe Zhao Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2013,第Null期

机译：羧基官能化二铁丙烷二硫代磺酸盐配合物的合成，表征和晶体结构
4. Synthesis and Characterization of Diiron(II) Complex with the Asymmetric Ligand Fixed into Internal Surface of Mesoporous Silica [C] . Yuji Kajita, Reiko Tsujimura, Hidekazu Arii, Asian International Conference on Advanced Materials . 2006

机译：与介孔二氧化硅内表面固定到不对称配体的二龙（II）复合物的合成与表征
5. Synthesis, characterization and mesomorphic behavior of platinum diimine/dithiolate complexes. [D] . Dibrov, Sergey Mikhailovich. 2002

机译：铂二亚胺/二硫醇盐配合物的合成，表征和介晶行为。
6. Characterization of a Borane σ Complex of a Diiron Dithiolate: Model for an Elusive Dihydrogen Adduct [O] . Noémie Lalaoui, Toby Woods, Thomas B. Rauchfuss, -1

机译：Dithio dithiolate硼烷σ配合物的表征：难以捉摸的二氢加合物的模型
7. Synthesis and Structural Characterization of Diiron Dithiolate Complex (μ-SCH2)2NCH2PhFe2(CO)52(Ph2PCH2CH2CH2PPh2) with Bridging Diphosphine Ligand [O] . Wei Gao, Lian-Qi Tian, Jing Yang 2014

机译：用桥接二膦配体的二龙二硫酸二硫酸酯复合物（μ-SCH2）2NCH2PHFE2（CO）5 2（PH2PCH2CH2CH2PH2PPH2）的合成及结构表征

Synthesis and Structural Characterization of a Novel Carboxy-Functionalized Diiron Dithiolate Complex

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