首页> 外文期刊>Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry >Cyclization of the Semicarbazones to 1,3,4-Oxadiazole Derivatives Using Ceric Ammonium Nitrate as Oxidant
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Cyclization of the Semicarbazones to 1,3,4-Oxadiazole Derivatives Using Ceric Ammonium Nitrate as Oxidant

机译:以硝酸铈铵为氧化剂将半咔唑酮环化为1,3,4-恶二唑衍生物

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摘要

Cyclization of the semicarbazones to 1,3,4-oxadiazole using ceric ammonium nitrate as oxidant was studied. 2-Imino-1,3,4-oxadiazolines can be produced from semicarbazones, which undergo thermolysis to amides. Benzoic acid benzylidene bydrazide can also be cyclized to 2-methoxy-2-phenyl-1,3,4-oxadiazole in the presence of ceric ammonium nitrate and methanol.
机译:以硝酸铈铵为氧化剂,对半咔唑环化为1,3,4-恶二唑进行了研究。可以从半咔唑酮生产2-Imino-1,3,4-恶二唑啉,将其热分解为酰胺。在硝酸铈铵和甲醇的存在下,苯甲酸苄叉肼也可以环化成2-甲氧基-2-苯基-1,3,4-恶二唑。

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