Hydrothermal Synthesis and Crystal Structure of 1D Zigzag Chain [Zn(Hbsal)_2(4,4'-bipy)]_n

摘要

A novel coordination polymer of [Zn(Hbsal)_2(4,4'-bipy)]_n (Hbsal = 5-bromosalicylate, 4,4'-bipy = 4,4'-bipyridine) was synthesized by hydrothermal reaction and characterized by elemental analysis and X-ray single crystal diffraction. The crystal is monoclinie, space group C2/c witha = 20.561(4),b = 9.207(2), c = 14.769(3) A, α = 90°, β= 121.92(3)°, γ=90°,M_r = 653.58, V = 2373.0(8) A~3, D_c= 1.829 g/cm~3, F(000) = 1288 and Z = 4. The structure analysis shows that the complex exhibits a 1D zigzag chain structure.