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Systematic Investigation of Products Formed During Synthesis of Ni, W, Cu/Kieselguhr Catalyst by X-ray Diffraction

机译:X射线衍射合成Ni,W,Cu / Kieselguhr催化剂过程中形成的产物的系统研究

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摘要

Catalytic hydrogenolysis of sucrose is industrially important for the production of glycerol, ethylene glycol and propylene glycol. Nickel(II) catalyst promoted by W and Cu and supported on kieselguhr was synthesized in the aqueous medium by co-precipitating compounds of nickel, copper and tungsten on kieselguhr from solution of their salts using sodium carbonate. The composition of the constituents presentalong with desired catalyst formed during synthesis has profound impact on its catalytic activity. Therefore, the present study deals with the synthesis and characterization of all the constituents' major and minor products formed during synthesis of catalyst both unreduced and reduced by X-ray diffraction studies. The results indicated the formation of appreciable amount of nickel hydro silicates and small amount of ionic nickel carbonate and nickel carbonate hydrate in the unreduced catalyst. Besides the formation of major product, hetropoly acid and nickel tungsten silicide were also present in the unreduced catalyst. The catalyst was reduced at 600 ℃ before carrying thehydrogenolysis reactions and the reduced products were also analyzed for the composition, when the catalyst activity was the maximum. The various chemical reactions involved in the synthesis procedure have been discussed.
机译:蔗糖的催化氢解对于生产甘油,乙二醇和丙二醇在工业上很重要。 W和Cu促进并负载在硅藻土上的镍(II)催化剂是通过在碳酸钠中从镍,铜和钨的盐溶液中共沉淀镍,铜和钨的化合物在水介质中合成的。与合成过程中形成的所需催化剂一起存在的组分的组成对其催化活性具有深远的影响。因此,本研究涉及通过X射线衍射研究未还原和还原的催化剂合成过程中形成的所有成分的主要和次要产物的合成和表征。结果表明在未还原的催化剂中形成了相当数量的氢硅酸镍和少量的离子性碳酸镍和碳酸镍水合物。除了形成主要产物外,未还原的催化剂中还存在杂多酸和硅化镍钨。在催化剂进行最大的氢解反应之前,先于600℃还原,并分析还原产物的组成。讨论了合成过程中涉及的各种化学反应。

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