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Synthesis and Crystal Structure of Complex [Cd(CH3COO)2(C7H6N2S)2]

机译:配合物[Cd(CH3COO)2(C7H6N2S)2]的合成与晶体结构

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摘要

A mixed complex [Cd(CH3COO)2(C7H6N2S)2] was synthesized based on the reaction of cadmium acetate and 2-aminobenzothiazole(C7H6N2S) in methanol medium. The structure of this complex was characterized by elemental analysis and IR spectrum. The crystalstructure of the compound [Cd(CH3COO)2(C7H6N2S)2] was also determined by X-ray single crystal diffraction. The crystal belongs tocrystal orthorhombic system with space group Pna2(l) and crystallographic data of the compound are: a = 0.88831(15) nm, b = 2.7449(3) nm, c = 0.90103(16) nm, α = β = γ = 90°, V = 2.1970(6) nm~3; D_c = 1.605 g/cm~3; Z = 4; F(000) = 1064; m = 1.214 mm~(-1).
机译:基于乙酸镉与2-氨基苯并噻唑(C7H6N2S)在甲醇介质中的反应,合成了混合配合物[Cd(CH3COO)2(C7H6N2S)2]。该复合物的结构通过元素分析和IR光谱表征。化合物[Cd(CH3COO)2(C7H6N2S)2]的晶体结构也通过X射线单晶衍射测定。该晶体属于具有空间群Pna2(l)的正交晶体系统,该化合物的晶体学数据为:a = 0.88831(15)nm,b = 2.7449(3)nm,c = 0.90103(16)nm,α=β=γ = 90°,V = 2.1970(6)nm〜3; D_c = 1.605 g / cm〜3; Z = 4; F(000)= 1064; m = 1.214毫米〜(-1)。

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