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A Mild and Efficient Method for Synthesis of β-Enaminones using Melamine-Formaldehyde Resin Supported H~+ Under Solvent Free Conditions

机译:三聚氰胺-甲醛树脂负载的H〜+无溶剂条件下温和高效的合成β-烯胺的方法

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摘要

A green and efficient practical approach is developed for the synthesis of β-enaminones using melamine-formaldehyde resin supported H~+ (MFRH) as a mild and inexpensive catalyst in solvent-free media. The present method was performed by combining low cost and readily available amines, 1,3-dicarbonyls and melamine-formaldehyde resin supported HP (MFRH) as a catalyst. This method is applicable to both cyclic and acyclic ketones with aromatic and aliphatic amines, and provides several advantages such as environmental friendliness, low cost, good yields and simple workup procedure.
机译:开发了一种绿色高效的实用方法,该方法使用三聚氰胺-甲醛树脂负载的H〜+(MFRH)作为无溶剂介质中的温和廉价催化剂来合成β-烯酮。通过组合低成本且容易获得的胺,1,3-二羰基化合物和三聚氰胺-甲醛树脂负载的HP(MFRH)作为催化剂来执行本方法。该方法适用于带有芳族和脂族胺的环状和非环状酮,并具有许多优点,例如环境友好,成本低,产率高以及后处理步骤简单。

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