Synthesis and Characterization of 2-{[(6-{[(2-Hydroxyphenyl)-methylidene]amino}-2-pyridyl)imino]methyl}phenol and Its Zn(II) Complex

摘要

2- {[(6- {[(2-Hydroxyphenyl)methylidene]amino} -2-pyridyl)imino]-methyl}phenol (HMA) were synthesized and characterized. Zn(II) metal complex of this ligand prepared by reaction of Zn(II) acetate with HMA in dry acetonitrle. Characterization of the ligand and its zinc(II) complex was made by microanalyses,FT-IR,~1H NMR,~(13)C NMR and UV-visible spectroscopy,in the light of these results,it was suggested that one ligand coordinate to each metal atom to form octahedral complex of Zn(II). The zinc(II) complex was characterized by elemental analysis (C,H,N),FT-IR,electronic spectra and molar conductance measurements. The elemental analysis data suggest the stpichiometry to be 1:1 [M:L] ratio formation. The molar conductance measurements reveal the presence of 1:1 electrolytic nature complex.