Commercial Cu-SAPO-34 catalysts suffer from poisoning of SO2 in the selective catalytic reduction of NOx with NH3 (NH3-SCR). It is challenging to inhibit the deposition of ammonium hydrogen sulfate (ABS) and the sulfation of Cu species in the presence of SO2. Here, we originally demonstrate that sulfur-philic ZCuOH sites could be converted into sulfur-phobic Z2Cu sites in Cu-SAPO-34 by a hydrothermal aging (HA) method, thereby improving the SO2 resistance. After the HA treatment, the SO2 adsorption capacity and ABS deposition over catalysts are both reduced by 30–40% compared to that over the original counterpart. Moreover, SO2-induced overoxidation and polymerization of Cu species are also suppressed, thus maintaining the redox balance of the NH3-SCR reaction. This work provides an effective approach to enhance the SO2 resistance of Cu-SAPO-34 catalysts via creating sulfur-phobic Z2Cu sites, which is of significance for practical applications.
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