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Synthesis of a new palladium salt using N-benzyl DABCO chloride and its application in Suzuki reaction

机译:N-苄基DABCO氯化物新型钯盐的合成及其在Suzuki反应中的应用

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摘要

A palladium catalyst was synthesized using N-benzyl DABCO chloride and palladium chloride. The structure of this catalyst was characterized and then the catalyst was used in Suzuki cross- coupling reaction of different aryl halides with arylboronic acids. All substrates afforded the corresponding products in good to high yields in the presence of low amounts of the catalyst. Under the heating conditions employed, cheaper and more available aryl chlorides gave relatively high yields in the Suzuki reaction.
机译:使用N-苄基DABCO氯化物和氯化钯合成钯催化剂。表征了该催化剂的结构,然后将该催化剂用于不同的芳基卤化物与芳基硼酸的Suzuki交联反应。在少量催化剂的存在下,所有底物均以良好至高收率提供了相应的产物。在所采用的加热条件下,较便宜和可用的芳基氯化物在铃木反应中给出了相对较高的产率。

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