Enhancement of Catalytic Activity and Selectivity for the Gaseous Electroreduction of CO2 to CO: Guidelines for the Selection of Carbon Supports

摘要

To secure the economic feasibility of electrochemical carbon dioxide reduction reaction (CO_2RR), a method of using support materials to reduce the amount of catalyst loading and increase catalytic activity for CO_2RR can be a solution. Herein, guidelines for selecting carbon support materials suitable for CO2RR are reported. In a gaseous CO_2-fed CO_2RR electrolyzer, an Ag nanoparticle-composited carbon nanocage (denoted as Ag/CNC) electrode exhibits an optimal performance for CO_2RR with a partialcurrent density of ≈400 mA cm~(-2). Ag/CNC showcases a uniformly dispersed morphology with Ag nanoparticles and sufficient hydrophobicity after the reaction to prevent flooding, which is known to inhibit the mass transfer of CO_2. Furthermore, the CNCspossess small amounts of carbon defects; this suppresses the catalytic activity for the hydrogen evolution reaction (HER), which is a side reaction of CO_2RR. Results of a three-stack cell experiment with the Ag/CNC electrode reveal the possibility of asupport-based strategy for achieving an industrial-level scaling of CO_2RR. This study suggests that the support material for CO_2RR should be considered not only on the basis of the morphology of carbon, uniform dispersion of Ag nanoparticles, and hydrophobicity of the electrode but also factors influencing the HER, such as carbon defects.