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首页> 外文期刊>Acta Crystallographica. Sect.C, Section C. Crystal Structure Communications >catena-PolyN-(4-amino-1,6-dihydro-1-methyl-5-nitroso-6-oxopyrimidin-2-yl)-(S)-glutamatohexaaqua-barium-mu-N-(4-amino-1,6-dihydro-1-methyl-5-nitroso-6-oxopyrimidin-2-yl)-(S)-glutamato: coordination polymer chains linked into a three-dimensional
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catena-PolyN-(4-amino-1,6-dihydro-1-methyl-5-nitroso-6-oxopyrimidin-2-yl)-(S)-glutamatohexaaqua-barium-mu-N-(4-amino-1,6-dihydro-1-methyl-5-nitroso-6-oxopyrimidin-2-yl)-(S)-glutamato: coordination polymer chains linked into a three-dimensional

机译:catena-PolyN-(4-amino-1,6-dihydro-1-methyl-5-nitroso-6-oxopyrimidin-2-yl)-(S)-glutamatohexaaqua-barium-mu-N-(4-amino-1,6-dihydro-1-methyl-5-nitroso-6-oxopyrimidin-2-yl)-(S)-glutamato: coordination polymer chains linked into a three-dimensional

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摘要

In the title complex, [Ba(C10H12N5O6)(2)(H2O)(6)](n) the Ba atom is nine-coordinated by six water ligands and three carboxylate O atoms. The Ba2+ cations and the anionic glutamate ligands form coordination polymer chains, and these chains are linked by pairs of N-H••• O hydrogen bonds and pairs of O-H••• O hydrogen bonds to form a continuous three-dimensional framework of cations and anions, which is reinforced by hydrogen bonds involving the water molecules.
机译:标题中复杂,[Ba (C10H12N5O6) (2) (H2O) (6)] (n)英航原子nine-coordinated六水配体和三个羧酸盐O原子。谷氨酸阴离子配体形成协调聚合物链,这些链是联系在一起的对N-H•牛,牛;和双O-H&BULL,公牛,公牛;债券,以形成一个连续的三维阳离子和阴离子的框架,这是强化了涉及水的氢键分子。

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