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首页> 外文期刊>Acta Crystallographica. Sect.C, Section C. Crystal Structure Communications >(3S)-Benzyl N-(1-hydroxy-2,5-dioxo-pyrrolidin-3-yl)carbamate: two-dimensional sheets built from O-H center dot center dot center dot O, N-H center dot center dot center dot O, C = O center dot center dot center dot C = O and C-H center dot center dot
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(3S)-Benzyl N-(1-hydroxy-2,5-dioxo-pyrrolidin-3-yl)carbamate: two-dimensional sheets built from O-H center dot center dot center dot O, N-H center dot center dot center dot O, C = O center dot center dot center dot C = O and C-H center dot center dot

机译:(3 s)苄N - (1-hydroxy-2,5-dioxo-pyrrolidin-3-yl) carbamate:二维表由点地中心中心导中心导O、- h中心点中心导中心导O、C = O中心导中心导中心点C = O和碳氢键中心导中心导

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摘要

The title compound, C10H12O5N2, crystallizes with two independent molecules in the asymmetric unit. The molecules in the crystal structure are arranged into one-dimensional substructural ribbon motifs stabilized by a combination of two O-H center dot center dot center dot O and three N-H center dot center dot center dot O intermolecular hydrogen bonds, and also augmented by short C=O center dot center dot center dot C=O carbonyl-carbonyl interactions. Two intermolecular C-H center dot center dot center dot O short contacts between adjacent ribbons generate complex two-dimensional sheets on the ab plane. Adjacent sheets are linked via C-H center dot center dot center dot pi(arene) interactions, resulting in a complex three-dimensional framework.
机译:标题化合物,C10H12O5N2,结晶两个独立的分子不对称单位。分子晶体结构排列成一维子结构带图案的稳定两种的组合地中心导中心导中心点O和三个点中心点中心点O - h中心分子间氢键,也增强通过简短的C = O中心导中心导中心点C = Ocarbonyl-carbonyl交互。分子间碳氢键中心导中心导中心点O短接触邻丝带在ab生成复杂的二维表飞机。导中心点中心导π(芳烃)交互,导致一个复杂的三维框架。

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