In situ-grown organo-lead bromide perovskite-induced electroactive gamma-phase in aerogel PVDF films: an efficient photoactive material for piezoelectric energy harvesting and photodetector applications

摘要

The unique combination of piezoelectric energy harvesters and light detectors progressively strengthens their application in the development of modern electronics. Here, for the first time, we fabricated a polyvinylidene fluoride (PVDF) and formamidinium lead bromide nanoparticle (FAPbBr(3) NP)-based composite aerogel film (FAPbBr(3)/PVDF) for harvesting electrical energy and photodetector applications. The uniform distribution of FAPbBr(3) NPs in FAPbBr(3)/PVDF was achieved via the in situ synthesis of FAPbBr(3) NPs in the PVDF matrix, which led to the stabilization of the gamma-phase. The freeze-drying process induced an interconnected porous architecture in the composite film, making it more sensitive to small mechanical stimuli. Owing to this unique fabrication technique, the constructed aerogel film-based nanogenerator (FPNG) exhibited an output voltage and current of similar to 26.2 V and similar to 2.1 mu A, respectively, which were 5-fold higher than that of the nanogenerator with the pure PVDF film. Also, the sensitivity of FPNG upon the irradiation of light was demonstrated by the output voltage reduction of similar to 38%, indicating its capability as a light sensing device. Furthermore, the prepared FAPbBr(3)/PVDF composite was found to be an efficient candidate for light detection applications. A simple planar photodetector was fabricated with the 8.0 wt% FAPbBr(3) NP-loaded PVDF composite, which displayed very high responsivity (8 A/W) and response speed of 2.6 s. Thus, this exclusive combination of synthesis and fabrication for the preparation of electro-active films opens a new horizon in the piezoelectric community for effective energy harvesting and light detector applications.