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An occurrence of cadmiferous phosphorite soil concretions in Jamaica

机译:牙买加钙质磷矿土壤结石的发生

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Bauxite exploration drilling revealed the presence of phosphate minerals through the chemical and XRD analysis of recovered drill hole samples at Spitzbergen, in Manchester Parish, Jamaica. A subsequent pit led to the discovery of phosphorite concretions composed of hard competent masses of finely crystalline fluorapatite, with some minor crandallite. The phosphorite contains anomalously high levels of Zn (>5000mgkg~(-1)), Cd (>1.1%), Ag (>20mgkg~(-1)), Be (>80mgkg~(-1)) and, to a lesser extent, U. Textural and geochemical evidence indicates that the phosphorite concretions were most likely formed by the replacement of limestone by secondary deposition proximal to fossil guano deposits, postulated to be Late Miocene or Pliocene sea-bird colonies. Mechanical dispersion of the phosphorite concretions through karst weathering processes has led to their wider spatial distribution than the original guano deposits. Subsequent weathering of the concretions and the admixture of their decomposition products into the bauxitic and Terra Rossa soils is postulated to be the cause of the widespread anomalous levels of Zn, Cd and Be in these soils in central Jamaica, and the elevated levels of P in the bauxite.
机译:铝土矿勘探钻探是通过对牙买加曼彻斯特教区斯皮次卑尔根的回收钻孔样品进行化学和XRD分析来发现磷酸盐矿的存在。随后的凹坑导致发现了由坚硬的细晶氟磷灰石块体和一些少量的方钠石组成的亚磷酸盐凝结物。该亚磷酸盐含有异常高水平的Zn(> 5000mgkg〜(-1)),Cd(> 1.1%),Ag(> 20mgkg〜(-1)),Be(> 80mgkg〜(-1)),并且在较小程度上,U。纹理和地球化学证据表明,亚磷酸盐凝结物最可能是由化石鸟粪沉积物附近的次生沉积(假定为中新世晚期或上新世海鸟殖民地)替代了石灰岩而形成的。通过岩溶风化过程对亚磷酸盐岩的机械分散导致其空间分布比原始鸟粪矿床更宽。据推测,随后的固结物风化及其分解产物混入到铝土和Terra Rossa土壤中,是造成牙买加中部这些土壤中Zn,Cd和Be广泛异常水平以及P中P含量升高的原因。铝土矿。

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