Enhanced electrocatalytic oxygen evolution of alpha-Co(OH)(2) nanosheets on carbon nanotube/polyimide films

摘要

The future of energy supply depends on innovative breakthroughs in the development of highly efficient, sustainable and low-cost systems for renewable energy conversion and storage. Water splitting is a promising and appealing solution. In this work, we report Co(OH)(2) on the carbon nanotube/polyimide film (PI/CNT-Co(OH)(2)) as an efficient electrocatalyst for the oxygen evolution reaction (OER). The PI/CNT film allows intimate growth of Co(OH)(2) nanosheets on its surface. The nanosheet structure of Co(OH)(2) and the underlying PI/CNT film facilitate the good OER performance of the PI/CNT-Co(OH)(2) film. Co(OH)(2) nanosheets on the PI/CNT film afford an earlier onset of oxygen evolution, a low overpotential of 317 mV and a small Tafel slope of 49 mV per decade in alkaline media. This work applies the PI/CNT film in water splitting to enhance the OER electrocatalytic activity of Co(OH)(2), which opens up a promising avenue for the exploration of highly active electrocatalysts that can replace noble-metal based catalysts for the OER.