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Effects of ozone on the catalytic combustion of carbon black

机译:臭氧对炭黑催化燃烧的影响

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摘要

Elimination of carbon particles emitted into air is one of the main environmental problems. In this study, the catalytic combustion of carbon particles has been investigated in the presence of Cu-Ce-Al oxides. The influence of ozonation on the catalytic and physico-chemical properties of Cu-Ce-Al oxides and carbon black (CB) on the reaction of carbon black combustion was examined by thermal analysis and EPR spectroscopy. All the catalysts except alumina are active in the reaction of CB combustion. Due to ozone pre-treatment the catalytic combustion of CB passes to lower temperatures. Ozonation influences the nature of CB increasing the concentration and the stability of free radicals interacting with carbon particulate. (C) 2004 Elsevier B.V. All rights reserved.
机译:消除排放到空气中的碳颗粒是主要的环境问题之一。在这项研究中,已经研究了在Cu-Ce-Al氧化物存在下碳颗粒的催化燃烧。通过热分析和EPR光谱研究了臭氧化对Cu-Ce-Al氧化物和炭黑(CB)催化和理化性质对炭黑燃烧反应的影响。除氧化铝外,所有催化剂均在CB燃烧反应中具有活性。由于进行了臭氧预处理,CB的催化燃烧达到较低的温度。臭氧化影响CB的性质,增加了CB的浓度和与碳微粒相互作用的自由基的稳定性。 (C)2004 Elsevier B.V.保留所有权利。

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