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Multi-component noble metal catalysts prepared by sequential deposition precipitation for low temperature decomposition of dioxin

机译:通过顺序沉积沉淀法制备的二恶英低温分解多组分贵金属催化剂

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摘要

To create a decomposition catalyst for the several pollutants with the necessary performance, we united noble metals of two and three different types by selective and successive deposition onto select mixed metal oxide supports. The catalytic oxidations of H_2, trimethylamine, o-chlorophenol and of dioxin derivatives over these multi-component noble metal catalysts were subsequently investigated. The ternary component catalyst, Au/Fe_2O_3-Pt/SnO_2-Ir/La_2O_3, showed greatly enahcned activity in the catalytic oxidation of o-chlorophenol and of dioxin at 423 K, indicating a catalytic activity enhancing (boosting) effect by the addition of the Ir/La_2O_3 catalyst that by itself shows low activity.
机译:为了创建具有必要性能的几种污染物的分解催化剂,我们通过选择性和连续沉积到选定的混合金属氧化物载体上,将两种和三种不同类型的贵金属结合在一起。随后研究了H_2,三甲胺,邻氯苯酚和二恶英衍生物在这些多组分贵金属催化剂上的催化氧化。三元催化剂Au / Fe_2O_3-Pt / SnO_2-Ir / La_2O_3在423 K时对邻氯苯酚和二恶英的催化氧化中显示出大大增强的活性,表明通过添加三价催化剂可增强(增强)催化活性。 Ir / La_2O_3催化剂本身显示出低活性。

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