MnO_x-CeO_2 mixed oxide catalysts for complete oxidation of formaldehyde:Effect of preparation method and calcination temperature

摘要

MnO_x-CeO_2 mixed oxides prepared by sol-gel method,coprecipitation method and modified coprecipitation method were investigated for the complete oxidation of formaldehyde.Structure analysis by H_2-TPR and XPS revealed that there were more Mn~(4+) species and richer lattice oxygen on the surface of the catalyst prepared by the modified coprecipitation method than those of the catalysts prepared by sol-gel and coprecipitation methods,resulting in much higher catalytic activity toward complete oxidation of formaldehyde.The effect of calcination temperature on the structural features and catalytic behavior of the MnO_x-CeO_2 mixed oxides prepared by the modified coprecipitation was further examined,and the catalyst calcined at 773 K showed 100% formaldehyde conversion at a temperature as low as 373 K.For the samples calcined below 773 K,no any diffraction peak corresponding to manganese oxides could be detected by XRD measurement due to the formation of MnO_x-CeO_2 solid solution.While the diffraction peaks corresponding to MnO_2 phase in the samples calcined above 773 K were clearly observed,indicating the occurrence of phase segregation between MnO_2 and CeO_2.Accordingly,it was supposed that the strong interaction between MnO_x and CeO_2,which depends on the preparation route and the calcination temperature,played a crucial role in determining the catalytic activity toward the complete oxidation of formaldehyde.