Catalytic Asymmetric Mannich Reaction of Isatin-derived N-Boc Imines with Malononitrile by Bis (imidazolidine)-derived Pincer Rh Complex

Takayoshi Arai; Takuya Tosaka; Satoru Kuwano

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Catalytic Asymmetric Mannich Reaction of Isatin-derived N-Boc Imines with Malononitrile by Bis (imidazolidine)-derived Pincer Rh Complex

机译：BIS（Imidazolidine）衍生的Pincer RH复合物与伊萨蛋白衍生的N-BOC的N-BOC的催化不对称Mannich反应

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摘要

A chiral bis(imidazolidine) NCN-rhodium complex (tBu-PhBidine- Rh(OAc)2: cat 2) catalyzed the asymmetric Mannich reaction of malononitrile with isatin-derived imines, which provided an efficient synthetic route for 3-amino-2-oxoindoline- 3-carboxylates.

机译：氧氨基氨酸-3-羧酸盐。

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来源
《Chemistry Select》 |2017年第24期|7368-7371|共4页
作者
Takayoshi Arai; Takuya Tosaka; Satoru Kuwano;
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作者单位

Soft Molecular Activation Research Center (SMARC) Molecular Chirality Research Center (MCRC), and Department of Chemistry Graduate School of Science Chiba University 1-33 Yayoi, Inage, Chiba 263-8522 (Japan);

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原文格式 PDF
正文语种英语
中图分类 Online;
关键词
Isatin; Mannich reaction; asymmetric catalysisdicyanmethaneimines;

机译：伊萨汀;曼尼奇反应;不对称催化甲烷印异分析;

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Catalytic Asymmetric Mannich Reaction of Isatin-derived N-Boc Imines with Malononitrile by Bis (imidazolidine)-derived Pincer Rh Complex

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