Multi-Color Excitonic Emissions in Chemical Dip-Coated Organolead Mixed-Halide Perovskite

摘要

Organolead mixed-halide perovskites capable of emitting multiple colors not only allow the fabrication of compact devices but also improves the functionality of light emitting devices beyond conventional displays. Here we demonstrate a cost-effective chemical dip-coating technique to grow highly reproducible methylammonium-lead-halide perovskite film, which exhibits highly efficient multi-color emissions of red, green and ultraviolet. The power- and temperature-resolved cathodoluminescence analyses reveal that these emissions are attributed to localized excitions with thermal activation energies of 27, 29 and 57 meV. The non-linear fitting of these emission band widths within the frame work of Boson model reveals that excitons are strongly coupled to the lattice with energy of 28 meV, which is consistent with the Raman measurement. This work presents an effective method for the deposition of high-quality and large-area perovskite film, which could be useful for high-performance multi-color display devices.