Cobalt-Based MOF-Derived CoP/Hierarchical Porous Carbon (HPC) Composites as Robust Catalyst for Efficient Dehydrogenation of Ammonia-Borane

摘要

Transition-metal phosphides (TMP), particularly cobalt phosphide (CoP) has drawn considerable attention in heteroge- neous catalysis during the past few years due to their robust stability, corrosion resistance and low cost. In this work, a series of hierarchically porous carbon supported non-precious CoP NPs by using Co–MOF-74 as self-sacrificed templates have been synthesized through a stepwise calcinations and phosphoriza- tion method.