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Three-Component Acylation/Peroxidation of Alkenes through Visible-Light Photocatalysis

机译:通过可见光光催化的烯烃三分解酰化/过氧化

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摘要

A three-component acylation/peroxidation of alkenes through visible-light photocatalysis was described. The acyl radical was generated by a hydrogen atom transfer process and enabled the radical addition and peroxidation. Various indole-3-carbal- dehyde and styrene derivatives were subjected to the current visible light photochemical conditions, delivering β-peroxy- ketones in moderate to good isolated yields.
机译:描述了通过可见光光催化的三分量酰化/过氧化。 酰基自由基是通过氢原子转移过程产生的,并使自由基添加和过氧化。 对各种吲哚-3-脱氢和苯乙烯衍生物进行了当前的可见光光化学条件,以中度至良好的分离产率递送β-过敏 - 酮。

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