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Modern Trends in the Applications of Perovskites for Selective Organic Transformations

机译:钙钛矿应用于选择性有机转化的现代趋势

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Perovskites have captivated the interest of contemporary synthetic chemists in both the academic and industrial sector due to their multifarious physicochemical properties like excellent thermal stability, oxygen mobility substitution of A and B cations. These perovskite based mixed metal oxides effectively promote selective organic transformations like selective oxidation reactions, selective hydrogenation reactions, nitro to amine reduction, carbon-carbon and carbon hetero- bond forming reactions. Furthermore, these mixed metal oxide perovskites have been investigated for the multi-component domino reactions for synthesis of valuable organic compounds. Recently, metal halide perovskites have emerged as futuristic materials for the catalytic and photocatalytic selective organic transformations to form valuable organic compounds. The present review mainly addresses the recent developments in the catalytic and photocatalytic applications of perovkites in organic synthesis in the past 10 years.
机译:由于其多种物理化学特性,例如出色的热稳定性,A和B阳离子的氧气迁移率取代,钙钛矿吸引了当代合成化学家在学术和工业部门中的兴趣。这些基于钙钛矿的混合金属氧化物有效地促进了选择性有机转化,例如选择性氧化反应,选择性氢化反应,硝基对胺还原,碳碳和碳杂键形成反应。此外,已经研究了这些混合金属氧化物钙钛矿的多组分多米诺反应,以合成有价值的有机化合物。最近,金属卤化物钙钛矿已成为催化和光催化选择性有机转化的未来材料,形成有价值的有机化合物。本综述主要介绍了过去10年中钙化物在有机合成中的催化和光催化应用中的最新发展。

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