Palladium-Catalyzed Three-Component Carbocarbonation of Arynes: Expeditious Synthesis of o-Alkylated Arylacrylates and Stilbenes

Yao Tuanli; Hui Jiazhe; Liu Tao; Li Tao

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Palladium-Catalyzed Three-Component Carbocarbonation of Arynes: Expeditious Synthesis of o-Alkylated Arylacrylates and Stilbenes

机译：钯 - 催化的雄激催化三分 - 碳碳酸碳化物：迅速合成O-烷基化芳基丙烯酸酯和斯蒂芬

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摘要

A palladium-catalyzed multicomponent reaction involving olefin-tethered aryl iodides, arynes, and electrophilic alkenes has been developed for straightforward synthesis of o-alkylated arylacrylates and stilbenes through tandem intramolecular Heck cyclization/aryne dicarbofunctionalization.

机译：钯催化的多组分反应涉及烯烃栓系芳基碘化物、芳基和亲电烯烃，可通过串联分子内Heck环化/芳基二碳官能化直接合成o-烷基化芳基丙烯酸酯和二苯乙烯。

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《The Journal of Organic Chemistry》 |2021年第8期|共12页
作者
Yao Tuanli; Hui Jiazhe; Liu Tao; Li Tao;
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作者单位

Shaanxi Univ Sci &

Technol Coll Chem &

Chem Engn Key Lab Chem Addit China Natl Light Ind Xian 710021 Peoples R China;

Shaanxi Univ Sci &

Technol Coll Chem &

Chem Engn Key Lab Chem Addit China Natl Light Ind Xian 710021 Peoples R China;

Shaanxi Univ Sci &

Technol Coll Chem &

Chem Engn Key Lab Chem Addit China Natl Light Ind Xian 710021 Peoples R China;

Chinese Acad Agr Sci CAAS Shanghai Vet Res Inst Shanghai 200241 Peoples R China;

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正文语种 eng
中图分类有机化学;
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Palladium-Catalyzed Three-Component Carbocarbonation of Arynes: Expeditious Synthesis of o-Alkylated Arylacrylates and Stilbenes

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