A green method for Mn2+ and NH4+-N removal in electrolytic manganese residue leachate by electric field and phosphorus ore flotation tailings

摘要

High concentrations of manganese (Mn2+) and ammonia nitrogen (NH4+-N) in electrolytic manganese residue leachate (EMRL) have seriously polluted the environment. In this study, electric field and phosphorus ore flotation tailings (POFTs) were used for Mn2+ and NH4+-N removal in EMRL firstly. The effects of the liquid acid ratios, reaction temperature, current density, initial pH and stable pH of the solution, characteristics of EMRL and POFTs, and removal mechanism of NH4+-N and Mn2+ were investigated. The results indicated that an electric field enhanced the leaching of POFTs and promoted the adsorption and precipitation of Mn2+ and NH4+-N. The concentrations of Mn2+, NH4+-N, PO43- and F- in EMRL were 0.12 mg/L, 9.2 mg/L, 0.09 mg/L, and 0.24 mg/L, respectively, which were within the permitted level for the integrated wastewater discharge standard (GB8978-1996) after adjusting the second stable pH to 10.0. Mn2+ was mostly remove in the form of Mn(OH)(2), MnOOH, Mn-5(OH)(4)(PO4)(2) and MnO2. NH4+-N was mostly remove as NH4MgPO4 center dot 6H(2)O. The phosphate precipitation obtained could be used as market fertilizer. This study provided a new research idea for EMRL harmless disposal and POFTs resource utilization.