Bistable Elastic Electrochromic Ionic Gels for Energy-Saving Displays

摘要

The diversification of electrochromic materials greatly expands the application fields of electrochromic devices. However, highly flexible electrochromic materials remain challenging due to the inherent limitations associated with the existing electrochromic processes. Inspired by the hydrogen bonding effect in the hydrogel structure, a highly elastic and bistable electrochromic ionic gel based on a hydrogen bonding cross-linking network is prepared by solution polymerization having excellent tensile resilience, uniform coloring, reversible switching (<= 24.3 s), maximum transmittance change (>= 80%), bistability (54 h), reversibility (>500 cycles), and coloration efficiency (>= 85.3 cm(2).C-1). This method has been used to develop bistable electrochromic displays. The unconventional exploration of the bistable design principle may provide a new idea for the realization of bistable electrochromic devices.