Rapid detection of pesticides in honey by solid‐phase micro‐extraction coupled with electrospray ionization mass spectrometry

Choi Yi‐Ching; Ng Tsz‐Tsun; Hu Bin; Li Rong; Yao Zhong‐Ping

摘要

Abstract > Detection of pesticide residues in food samples is important for safeguarding food quality and safety. Conventional approaches for detection of pesticides in food samples typically involve labour‐intensive and time‐consuming sample pretreatment and chromatographic separation. In this study, solid phase micro‐extraction fibres were used to rapidly extract and enrich pesticides in honey, a popular agricultural product with complex matrix, and then directly coupled with electrospray ionization mass spectrometry for qualitative and quantitative analysis. Three pesticides, ie, atrazine, benalaxyl, and pirimicarb, were investigated using the technique and their analytical performances were evaluated. The limits of detection and limits of quantitation of all the three pesticides could fulfil the cut‐off values of the international standard. Linear calibration curves were constructed with good R 2 coefficients, and the accuracy and precision were in acceptable ranges for all the pesticides. The analysis time is much reduced, with only minimum sample preparation and no chromatographic separation involved. The technique is simple and easy to set up, and can be extended for analysis of other analytes and sample systems. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><abstract type=“main”xml:lang=“en”> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" > 著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-34906/'>《Journal of mass spectrometry: JMS 》</a> <b style="margin: 0 2px;">|</b><span>2020年第2期</span><b style="margin: 0 2px;">|</b> <span>共6页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Choi Yi‐Ching&option=202" target="_blank" rel="nofollow">Choi Yi‐Ching;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ng Tsz‐Tsun&option=202" target="_blank" rel="nofollow">Ng Tsz‐Tsun;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hu Bin&option=202" target="_blank" rel="nofollow">Hu Bin;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Li Rong&option=202" target="_blank" rel="nofollow">Li Rong;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yao Zhong‐Ping&option=202" target="_blank" rel="nofollow">Yao Zhong‐Ping;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>State Key Laboratory of Chemical Biology and Drug Discovery Food Safety and Technology Research Centre and Department of Applied Biology and Chemical TechnologyThe Hong Kong Polytechnic UniversityHong Kong SAR China;</p> <p>State Key Laboratory of Chemical Biology and Drug Discovery Food Safety and Technology Research Centre and Department of Applied Biology and Chemical TechnologyThe Hong Kong Polytechnic UniversityHong Kong SAR China;</p> <p>State Key Laboratory of Chemical Biology and Drug Discovery Food Safety and Technology Research Centre and Department of Applied Biology and Chemical TechnologyThe Hong Kong Polytechnic UniversityHong Kong SAR China;</p> <p>Inspection &</p> <p>Quarantine Technology CenterZhongshan Entry‐Exit Inspection &</p> <p>Quarantine BureauZhongshan Guangdong China;</p> <p>State Key Laboratory of Chemical Biology and Drug Discovery Food Safety and Technology Research Centre and Department of Applied Biology and Chemical TechnologyThe Hong Kong Polytechnic UniversityHong Kong SAR China;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li> <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span> <a href="https://www.zhangqiaokeyan.com/clc/1187.html" title="分析化学">分析化学 ;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=direct coupling&option=203" rel="nofollow">direct coupling;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=electrospray ionization mass spectrometry&option=203" rel="nofollow">electrospray ionization mass spectrometry;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=honey&option=203" rel="nofollow">honey;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=pesticides&option=203" rel="nofollow">pesticides;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=solid‐phase microextraction&option=203" rel="nofollow">solid‐phase microextraction;</a> </p> <div class="translation"> 机译：None; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-chemical-letters_thesis/0201290878503.html">Rapid detection of pesticide residues in Chinese herbal medicines by molecularly imprinted membrane electrospray ionization mass spectrometry</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chunmei Wu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Chunmei Wu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Tianyi Li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Tianyi Li,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Dongju Li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Dongju Li,</a> <a href="/journal-foreign-16399/" target="_blank" rel="nofollow" class="tuijian_authcolor">中国化学快报（英文版） .</a> <span>2021</span> <span>,第007期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-chemical-letters_thesis/0201255685220.html">Metabolism Study on Tobacco-specific N-Nitrosamines in Rabbit by Solid-phase Extraction and Liquid Chromatography-electrospray Ionization-mass Spectrometry Method</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jian Xun ZHANG&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jian Xun ZHANG,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Chen Chen LI&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Chen Chen LI,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Zheng CHEN&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Zheng CHEN,</a> <a href="/journal-foreign-16399/" target="_blank" rel="nofollow" class="tuijian_authcolor">中国化学快报（英文版） .</a> <span>2005</span> <span>,第012期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-chemistry_thesis/0201251276798.html">Combination of Solid-Phase Micro-Extraction and Direct Analysis in Real Time-Fourier Transform Ion Cyclotron Resonance Mass Spectrometry for Sensitive and Rapid Analysis of 15 Phthalate Plasticizers in Beverages</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mengxi Wu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mengxi Wu,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Haoyang Wang&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Haoyang Wang,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Guoqing Dong&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Guoqing Dong,</a> <a href="/journal-foreign-4769/" target="_blank" rel="nofollow" class="tuijian_authcolor">中国化学（英文版） .</a> <span>2015</span> <span>,第002期</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/070402862617.html">Micro-solid-phase extraction coupled to desorption electrospray ionization-high-resolution mass spectrometry for the analysis of explosives in soil</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bianchi Federica&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Bianchi Federica,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gregori Adolfo&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gregori Adolfo,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Braun Gabriele&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Braun Gabriele,</a> <a href="/journal-foreign-19037/" target="_blank" rel="nofollow" class="tuijian_authcolor">Analytical and bioanalytical chemistry .</a> <span>2015</span> <span>,第3期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：微固相萃取结合解吸电喷雾电离-高分辨率质谱法分析土壤中的炸药</span> </p> </li> <li> <div> <b>5. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704028181398.html">Coupling of micro-solid-phase extraction and internal extractive electrospray ionization mass spectrometry for ultra-sensitive detection of 1-hydroxypyrene and papaverine in human urine samples</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Han Jing&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Han Jing,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Liu Wei&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Liu Wei,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Su Rui&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Su Rui,</a> <a href="/journal-foreign-19037/" target="_blank" rel="nofollow" class="tuijian_authcolor">Analytical and bioanalytical chemistry .</a> <span>2019</span> <span>,第15期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：微固相萃取和内部萃取电喷雾电离质谱法的偶联，对人尿样中的1-羟基吡啶和罂粟碱进行超敏感检测</span> </p> </li> <li> <div> <b>6. </b><a class="enjiyixqcontent" href="/journal-foreign-detail/0704015070975.html">Identification of phenolic compounds in rosemary honey using solid-phase extraction by capillary electrophoresis-electrospray ionization-mass spectrometry.</a> <b>[J]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Arraez Roman D&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Arraez Roman D,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gomez Caravaca AM&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gomez Caravaca AM,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Gomez Romero M&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Gomez Romero M,</a> <a href="/journal-foreign-35436/" target="_blank" rel="nofollow" class="tuijian_authcolor">Journal of Pharmaceutical and Biomedical Analysis: An International Journal on All Drug-Related Topics in Pharmaceutical, Biomedical and Clinical Analysis .</a> <span>2006</span> <span>,第5期</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：固相萃取-毛细管电泳-电喷雾电离-质谱法鉴定迷迭香蜂蜜中的酚类化合物</span> </p> </li> <li> <div> <b>7. </b><a class="enjiyixqcontent" href="/academic-conference-foreign_meeting-257539_thesis/0705010485554.html">Urinary Metabolite Profiling using Solid-Phase Extraction and Direct Infusion Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry</a> <b>[C]</b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Bo Blanckenburg&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Bo Blanckenburg,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yuri van der Burgt&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Yuri van der Burgt,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Andre M Deelder&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Andre M Deelder,</a> <a href="/conference-foreign-257539/" target="_blank" rel="nofollow" class="tuijian_authcolor">American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics .</a> <span>2009</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：使用固相提取和直接输注电喷雾电离傅里叶变换离子回旋谐振质谱法的尿代谢物分析</span> </p> </li> <li> <div> <b>8. </b><a class="enjiyixqcontent" href="/academic-degree-foreign_mphd_thesis/02061627191.html">Advanced methods for the determination of pesticides in the environment: Combination of solid-phase extraction/cleanup and chemical ionization gas chromatography-mass spectrometry</a> <b>[D] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Mogadati, Paul Sudhakar&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Mogadati, Paul Sudhakar </a> <span>1999</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：测定环境中农药的先进方法：固相萃取/净化与化学电离气相色谱-质谱联用</span> </p> </li> <li> <div> <b>9. </b><a class="enjiyixqcontent" href="/academic-journal-foreign-pmc_detail_thesis/040005958790.html">A novel validated procedure for the determination of nicotine eight nicotine metabolites and two minor tobacco alkaloids in human plasma or urine by solid-phase extraction coupled with liquid chromatography-electrospray ionization-tandem mass spectrometry</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Eleanor I Miller&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Eleanor I Miller,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hye-Ryun K Norris&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hye-Ryun K Norris,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Douglas E Rollins&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Douglas E Rollins,</a> <span>-1</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：对于尼古丁的确定一种新的验证过程八种尼古丁代谢物和耦合用液相色谱 - 电喷雾串联质谱在人血浆或尿两个次要烟草生物碱通过固相萃取</span> </p> </li> <li> <div> <b>10. </b><a class="enjiyixqcontent" href="/open-access_resources_thesis/01000127076936.html">Rapid quantification of acetaminophen in plasma using solid‐phase microextraction coupled with thermal desorption electrospray ionization mass spectrometry</a> <b>[O] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Jentaie Shiea&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Jentaie Shiea,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Suhail Muzaffar Bhat&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Suhail Muzaffar Bhat,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Hung Su&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Hung Su,</a> <span>2020</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：使用固相微萃取与热解吸电喷雾电离质谱法一起快速定量等离子体中的乙酰氨基酚</span> </p> </li> <li> <div> <b>11. </b><a class="enjiyixqcontent" href="/ntis-science-report_pb_thesis/02071589840.html">Methods of Analysis by the U.S. Geological Survey National Water Quality Laboratory, Determination of Moderate-Use Pesticides and Selected Degradates in Water by C-18 Solid-Phase Extraction and Gas Chromatography/Mass Spectrometry;Water-resources investi</a> <b>[R] </b> . <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sandstrom, M. W.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Sandstrom, M. W.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Stroppel, M. E.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Stroppel, M. E.,</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Foreman, W. T.&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">Foreman, W. T.,</a> <span>2001</span> </span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：美国地质调查局国家水质实验室分析方法，C-18固相萃取和气相色谱/质谱法测定中等用途农药和水中选择的降解物;水资源调查</span> </p> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_detail_thesis/0201296834703.html">Rapid analysis of fifteen sulfonamide residues in pork and fish samples by automated on-line solid phase extraction coupled to liquid chromatography–tandem mass spectrometry</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Junmei Ma&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . Junmei Ma</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Sufang Fan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Sufang Fan</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lei Sun&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Lei Sun</a> <span> <a href="/journal-cn-57395/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 食品科学与人类健康（英文） </a> </span> <span> . 2020</span><span> ,第4期</span> </span> </div> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/academic-journal-cn_journal-chemical-physics_thesis/0201289497119.html">Detection of Tetracycline Antibiotics in Water by Dispersive Micro-solid Phase Extraction using Fe3O4@Cu3(btc)2 Magnetic Composite Combined with Liquid Chromatography-Tandem Mass Spectrometry</a> <b>[J]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yan-ni Li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . Yan-ni Li</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Yan-yun Hu&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Yan-yun Hu</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lei Ding&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Lei Ding</a> <span> <a href="/journal-cn-12046/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 化学物理学报 </a> </span> <span> . 2021</span><span> ,第002期</span> </span> </div> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/academic-conference-cn_meeting-17552_thesis/020221856170.html">Determination of Estrogens and Bisphenol A in Bovine Milk by Automated on-line C30 Solid-phase Extraction Coupled with High-performance Liquid Chromatography-mass Spectrometry</a> <b>[C]</b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Wei Yan&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . Wei Yan</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Ying Li&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Ying Li</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Lixia Zhao&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor">,Lixia Zhao</a> <span> <a href="/conference-cn-17552/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 第五届全国环境化学大会会议 </a> <span> <span> . 2008</span> </span> </div> </li> <li> <div> <b>4. </b><a class="enjiyixqcontent" href="/academic-degree-domestic_mphd_thesis/020313185725.html">Enrichment and Analysis of Food Pigments by Ionic Liquids Coated Magnetic Nanoparticles in Magnetic Solid Phase Extraction Coupled with Spectrophotometry</a> <b>[A] </b> <span> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Almojtaba Abd Alkhalig Ahmed Bakheet&option=202" target="_blank" rel="nofollow" class="tuijian_auth tuijian_authcolor"> . Almojtaba Abd Alkhalig Ahmed Bakheet</a> <span> . 2018</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06130415706208.html">MULTIPLE SOLID PHASE MICRO-EXTRACTION THERMAL DESORPTION IONIZATION DEVICE, MASS SPECTROMETER AND ANALYTICAL METHOD FOR MASS SPECTROMETRY</a> <b>[P]</b> . <span> 外国专利：  US2015144777A1 </span> <span> . 2015-05-28</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：固相微萃取热脱附电离装置，质谱仪及质谱分析方法 </span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06130417610362.html">METHOD FOR DETERMINATION OF STEROID HORMONES () IN AQUEOUS MATRIX BY SOLID-PHASE EXTRACTION (), DERIVATIZATION AND DETECTION BY GAS CHROMATOGRAPHY COUPLED WITH MASS SPECTROMETRY()</a> <b>[P]</b> . <span> 外国专利：  RO128664A8 </span> <span> . 2014-05-30</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：固相萃取（），质谱联用气相色谱法衍生化和检测测定基质中的甾体激素（） </span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130420241406.html">METHOD FOR DETERMINATION OF STEROID HORMONES () IN AQUEOUS MATRIX BY SOLID-PHASE EXTRACTION (), DERIVATIZATION AND DETECTION BY GAS CHROMATOGRAPHY COUPLED WITH MASS SPECTROMETRY()</a> <b>[P]</b> . <span> 外国专利：  RO128664A2 </span> <span> . 2013-07-30</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译：固相萃取（），质谱联用气相色谱法衍生化和检测测定基质中的甾体激素（） </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" id="enpatent55">相关主题</h3> <ul id="subject"> </ul> </div> </div> </div> </div> <div class="right rightcon"> <div class="details_img cardcommon clearfix" style="margin-bottom: 10px;display:none;" > </div> </div> </div> <div id="thesis_get_original1" class="downloadBth" style="bottom: 19px;z-index: 999;" onclick="ywcd('0704029325178','4',7,2,1,'',this,24)" class="delivery" prompt="010401" title="通过人工服务将文献原文发送至邮箱" >获取原文</div> <div class="journalsub-pop-up" style="display: none"> <div class="journal-sub"> <h2>期刊订阅</h2> <img src="https://cdn.zhangqiaokeyan.com/img/loginclose.png" alt="关闭" onclick="$('.journalsub-pop-up').hide()"> <p class="pardon">抱歉，该期刊暂不可订阅，敬请期待！</p> <p class="current">目前支持订阅全部北京大学中文核心（2020）期刊目录。</p> <div style="display: flex;margin-top: 69px;justify-content: space-between;"> <div class="no-sub" onclick="$('.journalsub-pop-up').hide()">暂不订阅</div> <div class="other-sub" onclick="continueSub('from=pc-detail')">继续订阅其他期刊</div> </div> </div> </div> <div class="right_btn"> <ul> <li class="gouwuche">  </li> <li class="yijian"> <a href="javascript:void(0);" onclick="link_analysis('/mycenter/auth/complaint.html',this)" title="意见反馈">意见反馈</a> </li> <li class="top"> <a href="javascript:scrollTo(0,0);" title="回到顶部">回到顶部</a> </li> <li class="shouye"> <a href="/" title="首页">回到首页</a> </li> </ul> </div> <div class="xllindexfooter"> <div class="xllindexfootercenter"> <div class="xllindexfooterleft left" > <div class="xllindexfooterleftli"> <ul> <li><a href="/about.html" title="关于掌桥">关于掌桥</a></li> <li><a href="/help/helpmap.html" title="资源导航">资源导航</a></li> <li><a href="/help/helpguide.html" title="新手指南">新手指南</a></li> <li><a href="/help/helpcenter.html" title="常见问题">常见问题</a></li> <li><a href="/sitemap.html" title="网站地图">网站地图</a></li> <li><a href="/help/helpcenter.html?type=9" title="版权声明">版权声明</a></li> </ul> </div> <div class="xllindexfooterleft"> <p class="xllindexfooterlefteamil">客服邮箱：kefu@zhangqiaokeyan.com</p> <div class="xllindexfooterlefttcp"> <div class="xllindexfooterpoliceiimg"></div> <div class="xllindexfooterpoliceispan"> <span>京公网安备：11010802029741号 </span> <span>ICP备案号：<a href="https://beian.miit.gov.cn" rel="nofollow" target="_blank" title="ICP备案号">京ICP备15016152号-6</a></span> <span>六维联合信息科技 (北京) 有限公司©版权所有</span> </div> </div> </div> </div> <div class="xllindexfooterright left"> <ul> <li> <p style="font-weight: bold;">客服微信</p> <div></div> </li> <li> <p style="font-weight: bold;">服务号</p> <div></div> </li> </ul> </div> </div> </div> <span id="0704029325178down" data-source="7," data-out-id="r5VkL+zsA4LqQ7rwpamRWkFPy8fxf04S6vqK0qGlRvyWv8nv/0ZETkss56JuX+yh," data-f-source-id="7" data-title="Rapid detection of pesticides in honey by solid‐phase micro‐extraction coupled with electrospray ionization mass spectrometry" data-price="20" data-site-name="" data-transnum="24" style="display:none;"></span> <input type="hidden" value="4" id="sourcetype"> <input type="hidden" value="34906" id="journalid"> <input type="hidden" value="1" id="inyn_provide_service_level"> <input type="hidden" value="https://cdn.zhangqiaokeyan.com" id="imgcdn"> <input type="hidden" value="1" id="isdeatail"> <input type="hidden" value="" id="syyn_indexed_database"> <input type="hidden" value="" id="servicetype"> <input type="hidden" id="pagename" value="Rapid detection of pesticides in honey by solid‐phase micro‐extraction coupled with electrospray ionization mass spectrometry"/> <input type="hidden" value="thesis_get_original" id="pageIdentification"> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery-1.12.4.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/lwlh_ajax.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zq.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/common.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/jquery.cookie.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/top.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/tip.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/login.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/down.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/search.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/newmail.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/searchtype.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/user/regist.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/zxs_solor/detail.js?v=5.7.9"></script> <script type="text/javascript" src="https://www.zhangqiaokeyan.com/statistics/static/pagecollection.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/tj.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/sse.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/pushbaidu.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/common/history.js"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/util/cookie.js?v=5.7.9"></script> <script type="text/javascript" src="https://cdn.zhangqiaokeyan.com/js/weipu/weipu.js?v=5.7.9"></script> </body> <script> function kefu(customization) { var from = GetQueryString("from"); if (from == null || from == "") { from = "other"; } var url = getWxWorkQrCode(55, from, customization); if (url == "" || typeof url == 'undefined') { url = "https://wework.qpic.cn/wwpic/994838_0LUTS-VqR0quT1N_1675665967/0"; } tipDocGuidance(url, '人工辅助获取外文期刊材料'); } $(function () { var weiPuStatus = getCookie('WeiPuStatus'); if (weiPuStatus) { tipWeiPuStatus(weiPuStatus); delCookie('WeiPuStatus'); } getFacetKeywordVoInId(); var sourcetype = $("#sourcetype").val(); var inyn_provide_service_level = $("#inyn_provide_service_level").val(); if ((sourcetype == 1 || sourcetype == 4) && inyn_provide_service_level != 4) { getJournal(); } }) </script> </html>