Mechanical and shape memory performance of shape memory polyurethane-based aligned nanofibers

摘要

In recent years, shape memory polyurethane (SMPU) as a smart material has been used in various applications owing to its desirable shape memory effect and biocompatibility. In this study, unidirectional SMPU nanofibers are innovated by electmspinning to clarify the mechanical and shape memory properties with nanofiber directions. The results showed that when the nanofiber alignment degree is 0 degrees (parallel to the tensile direction), the aligned SMPU nanofibers achieved the obvious improvement of tensile strength (increased to 135%) and elastic modulus (increased to 313%), compared with the random SMPU nanofiber. Moreover, the developed aligned nanofibers exhibited good ability against stress relaxation and creep under constant strain or constant stress conditions in cyclic loading. The aligned SMPU nanofibers with a 0 degrees alignment degree exhibited excellent shape memory properties with shape recovery rates larger than 93% and shape fixity rates larger than 90%, and a dramatic increase of shape recovery stress.