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首页> 外文期刊>Polymer international >Colorimetric detection of Hg2+ using a mixture of an anionic azo dye and a cationic polyelectrolyte in aqueous solution
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Colorimetric detection of Hg2+ using a mixture of an anionic azo dye and a cationic polyelectrolyte in aqueous solution

机译:使用阴离子偶氮染料的混合物和水溶液中的阳离子聚电解质的混合物比色检测Hg2 +

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Abstract > We investigated a colorimetric chemosensor for Hg 2+ based on a mixture of xylidyl blue I as an anionic organic dye and poly(diallyldimethylammonium chloride) as a cationic polyelectrolyte in an aqueous solution at pH?7.5. The addition of Hg 2+ to the mixture induced a bathochromic shift in the absorption spectra with a distinct color change from red to green which was readily identifiable by the naked eye, whereas the other metal ions gave rise to insignificant color changes. By contrast, upon adding Hg 2+ to xylidyl blue I alone, the solution underwent no significant change in color. Moreover, a stoichiometric ratio for the complex between xylidyl blue I and Hg 2+ in the presence of poly(diallyldimethylammonium chloride) was determined to be 1:1 by the absorption titration curve and Job's plot. Thus, the mixture can be used as a selective naked‐eye colorimetric chemosensor for Hg 2+ over other common metal ions. This study raises the possibility that the combination of an organic dye and an oppositely charged polyelectrolyte is a potential candidate for the easy construction of a new chemosensor system. ? 2018 Society of Chemical Industry </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译:</span><abstract xmlns=”http://www.wiley.com/namespaces/wiley“type=“main”xml:lang=“en”> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" > 著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-29710/'>《Polymer international 》</a> <b style="margin: 0 2px;">|</b><span>2018年第6期</span><b style="margin: 0 2px;">|</b> <span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Inoue Koshiro&option=202" target="_blank" rel="nofollow">Inoue Koshiro;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Aikawa Shunichi&option=202" target="_blank" rel="nofollow">Aikawa Shunichi;</a> <a href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Fukushima Yasumasa&option=202" target="_blank" rel="nofollow">Fukushima Yasumasa;</a> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> <p>Faculty of Science and EngineeringToyo UniversitySaitama Japan;</p> <p>Research Institute of Industrial TechnologyToyo UniversitySaitama Japan;</p> <p>Faculty of Science and EngineeringToyo UniversitySaitama Japan;</p> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li> <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span> <a href="https://www.zhangqiaokeyan.com/clc/1185.html" title="高分子化学(高聚物)">高分子化学(高聚物) ;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=colorimetric detection&option=203" rel="nofollow">colorimetric detection;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=chemosensor&option=203" rel="nofollow">chemosensor;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=mercury ion&option=203" rel="nofollow">mercury ion;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=XB‐I&option=203" rel="nofollow">XB‐I;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=polyelectrolyte&option=203" rel="nofollow">polyelectrolyte;</a> </p> <div class="translation"> 机译:比色度检测;化学传感器;汞离子;XB-I;聚电解质; </div> </li> </ul> </div> </div> <div class="literature cardcommon"> <div class="similarity "> <h3 class="all_title" id="enpatent66">相似文献</h3> <div class="similaritytab clearfix"> <ul> <li class="active" >外文文献</li> <li >中文文献</li> <li >专利</li> </ul> </div> <div class="similarity_details"> <ul > <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/academic-journal-cn_chinese-journal-chemistry_thesis/0201270230364.html">Sulfonated Hollow Covalent Organic Polymer: Highly-Selective 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Peking University 100871)</a> <span> <a href="/journal-cn-52847/" target="_blank" rel="nofollow" class="tuijian_authcolor"> . 中国化学快报:英文版 </a> </span> <span> . 1997</span><span> ,第6期</span> </span> </div> </li> </ul> <ul style="display: none;"> <li> <div> <b>1. </b><a class="enjiyixqcontent" href="/patent-detail/06130478573683.html">Stable aqueous solution of cationic groups and having vinyl copolymers and anionic surfactants or anionic polyelectrolytes</a> <b>[P]</b> . <span> 外国专利: <!-- 德国专利: --> DE2832944A1 </span> <span> . 1980-02-14</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:稳定的阳离子基团水溶液,具有乙烯基共聚物和阴离子表面活性剂或阴离子聚电解质 </span> </p> </li> <li> <div> <b>2. </b><a class="enjiyixqcontent" href="/patent-detail/06130471763228.html">PROCESS FOR THE SEPARATION OF SODIUM SULPHATE FROM AQUEOUS SOLUTIONS CONTAINING SODIUM SULFATE AND LESS THAN 2 BY WEIGHT OF ANIONIC OR CATIONIC CHLORIDE DYES, AS WELL AS DYE SOLUTIONS SO OBTAINED</a> <b>[P]</b> . <span> 外国专利: <!-- --> BR8501632A </span> <span> . 1985-12-03</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:从重量百分比小于2%的阴离子或阳离子氯化染料以及所含染料溶液的硫酸钠水溶液中分离硫酸钠的方法 </span> </p> </li> <li> <div> <b>3. </b><a class="enjiyixqcontent" href="/patent-detail/06130436003591.html">Anionic characteristic jisu or can stability thick aqueous solution of tetra- azo dye</a> <b>[P]</b> . <span> 外国专利: <!-- 日本专利: --> JP2007512393A </span> <span> . 2007-05-17</span> </div> <p class="zwjiyix translation" style="max-width: initial;height: auto;word-break: break-all;white-space: initial;text-overflow: initial;overflow: initial;"> <span>机译:阴离子特性或能稳定稠度的四偶氮染料水溶液 </span> </p> </li> </ul> </div> </div> </div> <div class="theme cardcommon" style="overflow: auto;display:none"> <h3 class="all_title" 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