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Thermal, structural and dynamical mechanical properties of hollow glass sphere-reinforced polypropylene composites

机译:中空玻璃球体增强聚丙烯复合材料的热,结构和动力学机械性能

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摘要

In the present study, the effect of maleic anhydride grafted polypropylene (MAPP) ratio on the thermal and dynamic mechanical properties of polypropylene/hollow glass spheres (PP/HGS) composites was investigated. Hollow glass spheres content was constant at 20 wt % and MA-g-PP was set at four different levels: 1, 5, 10 and 15 wt % in PP/HGS composites. The mechanical properties of polymer composites as a function of temperature were measured using dynamic mechanic analyzer. The oxidation induction times tests and thermal properties were carried out in thermogravimetric differential thermal analyzer in order to determine thermo-oxidative performance and thermal stability of the composites. Moreover, the x-ray diffraction (XRD), the Fourier transform infrared spectrophotometry and the scanning electron microscopy were used to analyze the structural characteristics of the polymer composites. The results demonstrated that the increased MAPP content enhanced dynamic mechanical and thermal oxidative aging properties of PP /HGS composites. The addition of MAPP did not alter the crystal structure according to XRD results.
机译:研究了马来酸酐接枝聚丙烯(MAPP)比例对聚丙烯/中空玻璃球(PP/HGS)复合材料热性能和动态力学性能的影响。中空玻璃球含量在20 wt%时保持不变,MA-g-PP设置为四个不同的水平:PP/HGS复合材料中的1、5、10和15 wt%。利用动态力学分析仪测量了聚合物复合材料的力学性能随温度的变化。在热重差热分析仪上进行了氧化诱导时间测试和热性能测试,以确定复合材料的热氧化性能和热稳定性。此外,还利用x射线衍射(XRD)、傅里叶变换红外分光光度法和扫描电子显微镜分析了聚合物复合材料的结构特征。结果表明,MAPP含量的增加提高了PP/HGS复合材料的动态力学性能和热氧老化性能。根据XRD结果,MAPP的加入没有改变晶体结构。

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