Green synthesis of a bromocresol purple/graphene composite and its application in electrochemical determination of 2,4,6-trichlorophenol

摘要

This paper describes a new strategy for the determination of 2,4,6-trichlorophenol (TCP) by using a poly(bromocresol purple)/electrochemically reduced graphene oxide composite film modified glassy carbon electrode (BCP/erGO/GCE). Field emission scanning electron microscopy (FESEM), Raman scattering spectra, X-ray photoelectron spectroscopy (XPS) and electrochemical methods were used to characterize the hybrid film. The BCP/erGO/GCE displayed excellent electrocatalytic activity for the oxidation of TCP without any pretreatment. Under optimum conditions, wide linear ranges of 5.0 x 10(-8) to 1.0 x 10(-6) M and 1.0 x 10(-6) to 1.3 x 10(-4) M were obtained for TCP, and the low detection limit was 5.0 x 10(-9) M. The BCP/erGO/GCE also exhibited a good reproducibility and excellent stability. As a demonstration, the method was applied to determine TCP in real water samples.