Thermo physical, optical and spectroscopic perspectives of molecular interactions in binary mixtures of Ethyl Lactate and Dimethyl Adipate at T=303.15-318.15 K and atmospheric pressure

摘要

Molecular interactions are evaluated in the binaries of Ethyl Lactate and Dimethyl Adipate using experimental values of density, ultrasonic velocity and refractive index over entire composition range as a function of temperature from 303.15 to 318.15 K at atmospheric pressure. Excess thermodynamic properties: excess molar volume, excess isentropic compressibility, excess isothermal compressibility, excess free length, excess isobaric thermal expansion coefficient, excess ultrasonic velocity and refractive index deviations are computed and fitted with Redlich-Kister polynomial equation to obtain the binary coefficients and the standard deviations. The existence of specific interactions in the mixture is revealed by excess properties, and further supported by partial molar properties. FTIR analysis ascertains the dominance of packing effect in the studied mixtures. Prediction of refractive index for the mixtures and pure components is done by several mixing rules with the estimation of relative errors. In addition, data are analysed by the Prigogine-Flory-Patterson theoretical model.