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A novel amperometric sensor based on intercalated montmorillonite modified carbon paste electrode for hydroquinone determination

机译:基于插层蒙脱土修饰碳糊电极的新型安培传感器用于对苯二酚的测定

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摘要

A simple and reliable amperometric sensor for hydroquinone (HQ) determination is developed based on an intercalated montmorillonite (MMT) modified carbon paste electrode (CPE). The modified CPE significantly enhances the peak current of HQ on cyclic voltammograms and differential pulse voltammograms. The electro-catalytic properties of the intercalated MMT can be attributed to the remarkably increased specific surface area of MMT after the intercalation process, which leads to a higher accumulation efficiency for HQ at this modified CPE. The modified CPE shows a linear range between 5 and 2000 μM HQ with a correlation coefficient of 0.9997, and the detection limit is as low as 0.57 μM (S/N = 3).
机译:基于插层蒙脱土(MMT)修饰的碳糊电极(CPE),开发了一种用于对苯二酚(HQ)测定的简单可靠的安培传感器。改性的CPE显着增强了HQ在循环伏安图和微分脉冲伏安图上的峰值电流。插层MMT的电催化性能可以归因于插层过程后MMT的比表面积显着增加,这导致在此改性CPE上HQ的积累效率更高。修改后的CPE的HQ线性范围介于5和2000μM之间,相关系数为0.9997,检测极限低至0.57μM(S / N = 3)。

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